Thanks for the reply.
I had removed the -recurse but clearly left it in my paste oops.
I can happily browse the LUNs via the following
https://FQDNof Vcenter/folder?dcPath=DATACENTRE&dsName=LUNNAME
Which confirms both the service and the ports are open.
The vmstores name within $ds does indeed have the correct FQDN of my vCenter server.